Just visit http://savedelete.com/17-elegant-and-high-quality-html5-website-templates-for… for the full list of 17 FREE HTML5 Website Templates.
Quite a nice screencast by Techmic.com that discusses HTML5, Microformats and CSS3. This 15 min video is ideal for a coffee break. You need QuickTime to watch it. Go to http://www.techmic.com/screencasts/html5-microformats-css3-1/ and click on the blue button on the left side of the screen.
Cool article by Smashing Magazine about CSS3 and HTML 5 layouts and how they will change things for Web Design in the future.